My_Test_Repo/force-app/main/default/lwc/navigateToHome/navigateToHome.js

import { LightningElement } from 'lwc';
import {NavigationMixin} from 'lightning/navigation';
export default class NavigateToHome extends NavigationMixin(LightningElement) {

    navigateToHome(){
        this[NavigationMixin.Navigate]({
            type:'standard__namedPage',
            attributes:{
                pageName:'home'
            }
        })
    }
}